ChemistryCore20 min read

Chemistry of the Environment

What air is made of, the pollutants we add, and treating water

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Practise the full question bank:

01

What clean air is made of

Dry air is roughly 78% nitrogen, 21% oxygen, about 1% argon, and a small but crucial 0.04% carbon dioxide, plus traces of other gases and variable water vapour. That tiny slice of CO₂ does an outsized amount of work — for plants, and for the climate.

02

Air pollutants and where they come from

Burning fuels — mostly in vehicles and power stations — adds gases that clean air does not contain:

PollutantSourceProblem it causes
Carbon monoxide (CO)incomplete combustion of fuelstoxic — binds to blood, stops it carrying oxygen
Sulfur dioxide (SO₂)burning sulfur-containing fuelsacid rain
Oxides of nitrogen (NOₓ)high-temperature combustion in enginesacid rain and smog
Particulates (soot)incomplete combustion, dieselrespiratory disease, dirties surfaces
03

The greenhouse effect

Some gases — chiefly carbon dioxide and methane — let sunlight in but trap the heat the Earth radiates back, warming the surface. A natural amount of this keeps the planet habitable; the problem is the extra we add.

Burning fossil fuels (coal, oil, gas) releases CO₂ faster than it is removed, raising its concentration and enhancing the greenhouse effect. The consequences — a warming climate, shifting weather, rising seas — are why cutting fossil-fuel use and its emissions matters.

04

Water

Water for drinking is made safe by treatment: filtration through beds of sand and gravel to remove solids, then chlorination to kill bacteria (and sometimes other steps). It matters because untreated water spreads disease.

Water is also a fine solvent, which is why pollution dissolves and spreads in it — fertiliser run-off, industrial waste and sewage all damage rivers and the life in them.

Test for water

Anhydrous copper(II) sulfate turns from white to blue in the presence of water, and cobalt chloride paper turns from blue to pink. To confirm it is pure water, check it boils at 100 °C and freezes at 0 °C.

05

A worked example

Worked example

A car engine emits carbon monoxide and oxides of nitrogen. Name the problem each causes, and what reduces them.

  1. Carbon monoxide comes from incomplete combustion and is toxic — it stops the blood carrying oxygen.CO binds to haemoglobin more strongly than oxygen.
  2. Oxides of nitrogen form in the hot engine and cause acid rain and smog.They dissolve in atmospheric water to form acids.
  3. A catalytic converter reduces both, turning CO and NOₓ into CO₂ and N₂.It catalyses reactions that convert the pollutants to harmless gases.

CO is toxic (blocks oxygen transport); NOₓ causes acid rain and smog; a catalytic converter changes both into CO₂ and N₂.

06

How pollutants form, and what they do

Most air pollution comes from burning fuels. Carbon monoxide (a toxic gas that stops blood carrying oxygen) forms from incomplete combustion where oxygen is limited. Sulfur dioxide comes from sulfur impurities in fuels, and oxides of nitrogen form when the intense heat of an engine makes nitrogen and oxygen from the air combine.

Sulfur dioxide and nitrogen oxides dissolve in rain to make acid rain, which kills trees and fish, and corrodes limestone buildings and metals. Soot (unburnt carbon) blackens buildings and harms lungs.

07

Reducing the impact

A catalytic converter in a car's exhaust turns pollutants into harmless gases — for example 2CO + O₂ → 2CO₂, and it reduces nitrogen oxides back to nitrogen. Power stations remove sulfur dioxide by flue-gas desulfurisation with calcium oxide or carbonate.

Carbon dioxide is different — it is not toxic, but as a greenhouse gas it traps outgoing heat and drives climate change: rising sea levels, more extreme weather and shifting habitats. Cutting it means burning fewer fossil fuels, using renewable energy and improving efficiency.

Greenhouse gases trap heat

Gases like CO₂ and methane let the Sun's energy in but absorb and re-emit the heat the Earth radiates back out. More of them means more trapped heat — a warmer planet.

08

Treating and testing water

Making water safe to drink takes several stages: sedimentation and filtration to remove solids, then chlorination to kill microbes. This makes it potable, but not chemically pure — dissolved salts remain.

To test for water, add anhydrous copper(II) sulfate (white → blue) or blue cobalt chloride paper (→ pink). To show water is pure, check that it boils at exactly 100 °C and freezes at 0 °C — dissolved substances would shift those points.

Practice questions

6 questions · 22 marks · full working on every one

Try each one on paper first, then open the working. The marks are shown where they are actually awarded, because that is where they are actually lost.

Short questions

4 · 10 marks

Two marks each, in the style of the short-question section of the paper. Answer in two or three lines.

SQ1[2 marks]
State the approximate percentages of the two main gases in clean, dry air.
Model answer

About 78% nitrogen and about 21% oxygen (the remaining ~1% is mostly argon with a little carbon dioxide).

Examiner tip. Roughly four-fifths nitrogen, one-fifth oxygen.

SQ2[2 marks]
Name a chemical test for water and its positive result.
Model answer

Add anhydrous copper(II) sulfate — it turns from white to blue in the presence of water (or blue cobalt chloride paper turns pink).

Examiner tip. These tests show water is present, not that it is pure — a boiling point of 100 °C shows purity.

SQ3[3 marks]
Explain how the carbon dioxide produced by burning fossil fuels contributes to climate change.
Model answer

Carbon dioxide is a greenhouse gas; it absorbs and re-emits heat (infrared radiation) that would otherwise escape, so the extra CO₂ traps more heat and raises average global temperatures.

Examiner tip. Greenhouse gases trap outgoing heat — more of them means more warming.

SQ4[3 marks]
Explain how the sulfur dioxide released by burning coal leads to acid rain and one of its effects.
Model answer

Sulfur impurities in the coal burn to sulfur dioxide, which dissolves in rainwater to form an acidic solution (sulfurous/sulfuric acid). This acid rain damages plants and forests, acidifies lakes killing fish, or corrodes limestone buildings and metals.

Examiner tip. Acidic non-metal oxide + rainwater → acid; name a concrete effect.

Long questions

2 · 12 marks

Theory and numerical together, as they appear in the long-question section.

LQ1[6 marks]
Rusting is a serious problem for iron structures.
  1. State the two substances needed for iron to rust. [2]
  2. Describe how galvanising protects iron and how it works even if the coating is scratched. [3]
  3. Name one other method of rust prevention. [1]
Mark scheme
  1. Water (moisture)[1]
  2. Oxygen (air)[1]
  3. Galvanising coats the iron with a layer of zinc[1]
  4. The zinc is more reactive than iron, so it corrodes/loses electrons in preference (sacrificial protection)[1]
  5. so the iron is protected even where the coating is scratched[1]
  6. Painting / oiling / greasing / coating with plastic (any one)[1]

Water + oxygen needed; galvanising = zinc coating that sacrificially protects (zinc more reactive) even if scratched; also painting/oiling.

Examiner tip. Sacrificial protection uses a more reactive metal that corrodes instead of the iron.

LQ2[6 marks]
Burning fossil fuels releases several gases into the atmosphere.
  1. Explain how carbon monoxide is formed and why it is harmful. [3]
  2. Explain how a catalytic converter reduces harmful emissions, giving one equation. [3]
Mark scheme
  1. Carbon monoxide forms by incomplete combustion[1]
  2. when there is not enough oxygen to make CO₂[1]
  3. it is toxic because it prevents the blood from carrying oxygen[1]
  4. The converter provides a catalyst surface where pollutants react[1]
  5. carbon monoxide is oxidised to carbon dioxide[1]
  6. 2CO + O₂ → 2CO₂ (and NOₓ is reduced to N₂)[1]

CO from incomplete combustion, toxic (stops blood carrying O₂); catalytic converter oxidises CO to CO₂ (2CO + O₂ → 2CO₂) and reduces NOₓ to N₂.

Examiner tip. Incomplete combustion → CO; catalytic converters both oxidise CO and reduce NOₓ.